Linking Mercury Contamination to Transport Dynamics in an Indonesian River: A Data-Driven Engineering Framework for ASGM-Impacted Watersheds

Authors

DOI:

https://doi.org/10.37385/jaets.v7i2.9121

Keywords:

Mercury Transport, ASGM Contamination, River Water Quality, Watershed Engineering, Environmental Risk Mitigation

Abstract

While Artisanal and Small-Scale Gold Mining (ASGM) severely contaminates watersheds with mercury (Hg), existing studies primarily diagnose pollution levels without identifying the underlying transport mechanisms or actionable engineering solutions. Addressing this gap, this study analyzes Hg concentrations, identifies physical transport vectors, and proposes a data-driven mitigation framework for the Kuantan River, Indonesia. A targeted spatial sampling (n=10) was conducted during the dry season (June 2025), with water samples analyzed using Cold Vapour Atomic Absorption Spectrometry (CVAAS). Results revealed gross contamination, with 100% of samples exceeding the World Health Organization (WHO) limit of 0.001 mg/L (ranging from 0.0027 to 0.0081 mg/L). The Heavy Metal Toxicity Load (HMTL) indicated critical toxicological risks (3.94–11.81). Crucially, Principal Component Analysis (PCA) identified Total Dissolved Solids (TDS) as the dominant spatial transport vector, demonstrating that Hg is predominantly particulate-bound rather than dissolved. To mitigate this, a hierarchical engineering framework is proposed, featuring source control (mercury-capturing retorts), pathway interruption (sedimentation basins to trap TDS), and receptor protection (point-of-use filtration). Although limited by a small sample size, this study extends foundational environmental engineering knowledge by linking statistical transport diagnostics to structural interventions, offering a replicable policy and watershed management blueprint for ASGM-impacted regions globally.

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References

Agustiani, T., Sulistia, S., Sudaryanto, A., Kurniawan, B., Poku, P. A., Elwaleed, A., Kobayashi, J., Ishibashi, Y., Anan, Y., & Agusa, T. (2025). Mercury contamination and human health risk by Artisanal Small-scale Gold Mining (ASGM) activity in Gunung Pongkor, West Java, Indonesia. Earth, 6(3), 67. https://doi.org/10.3390/earth6030067

Ajslev, J. Z. N., Møller, J. L., Andersen, M. F., Pirzadeh, P., & Lingard, H. (2022). The hierarchy of controls as an approach to visualize the impact of occupational safety and health coordination. International Journal of Environmental Research and Public Health, 19(5), 2731. https://doi.org/10.3390/ijerph19052731

Aldous, A. R., Tear, T., & Fernandez, L. E. (2024). The global challenge of reducing mercury contamination from artisanal and small-scale gold mining (ASGM): evaluating solutions using generic theories of change. Ecotoxicology, 33(4–5), 506–517. https://doi.org/10.1007/s10646-024-02741-3

Arıman, S., Soydan-Oksal, N. G., Beden, N., & Ahmadzai, H. (2024). Assessment of groundwater quality through hydrochemistry using Principal Components Analysis (PCA) and Water Quality Index (WQI) in Kızılırmak Delta, Turkey. Water, 16(11), 1570. https://doi.org/10.3390/w16111570

Badeenezhad, A., Soleimani, H., Shahsavani, S., Parseh, I., Mohammadpour, A., Azadbakht, O., Javanmardi, P., Faraji, H., & Babakrpur Nalosi, K. (2023). Comprehensive health risk analysis of heavy metal pollution using water quality indices and Monte Carlo simulation in R software. Scientific Reports, 13(1). https://doi.org/10.1038/s41598-023-43161-3

Basri, Sakakibara, M., & Sera, K. (2020). Mercury in soil and forage plants from artisanal and small-scale gold mining in the Bombana Area, Indonesia. Toxics, 8(1), 15. https://doi.org/10.3390/toxics8010015

Beckers, F., & Rinklebe, J. (2017). Cycling of mercury in the environment: Sources, fate, and human health implications: A review. Critical Reviews in Environmental Science and Technology, 47(9), 693–794. https://doi.org/10.1080/10643389.2017.1326277

Bolisetty, S., Peydayesh, M., & Mezzenga, R. (2019). Sustainable technologies for water purification from heavy metals: review and analysis. Chemical Society Reviews, 48(2), 463–487. https://doi.org/10.1039/c8cs00493e

Bose-O’Reilly, S., McCarty, K. M., Steckling, N., & Lettmeier, B. (2010). Mercury exposure and children’s health. Current Problems in Pediatric and Adolescent Health Care, 40(8), 186–215. https://doi.org/10.1016/j.cppeds.2010.07.002

Bridgewater, L. L. (2017). Standard methods for the examination of water and wastewater (23rd ed.). American Public Health Association.

Caeiro, S., Costa, M. H., Ramos, T. B., Fernandes, F., Silveira, N., Coimbra, A., Medeiros, G., & Painho, M. (2005). Assessing heavy metal contamination in Sado Estuary sediment: An index analysis approach. Ecological Indicators, 5(2), 151–169. https://doi.org/10.1016/j.ecolind.2005.02.001

Chambers, J. M. (2008). Basic Data and Computations BT - Software for Data Analysis: Programming with R (J. Chambers (ed.)). Springer New York. https://doi.org/10.1007/978-0-387-75936-4_6

Cinnirella, S., Pirrone, N., Horvat, M., & Kocman, D. (2013). Daysimetric mapping of mercury emissions from contaminated sites. E3S Web of Conferences, 1, 7007. https://doi.org/10.1051/e3sconf/20130107007

Dethier, E. N., Sartain, S. L., & Lutz, D. A. (2019). Heightened levels and seasonal inversion of riverine suspended sediment in a tropical biodiversity hot spot due to artisanal gold mining. Proceedings of the National Academy of Sciences, 116(48), 23936–23941. https://doi.org/10.1073/pnas.1907842116

Di Stasio, L., Gentile, A., Tangredi, D. N., Piccolo, P., Oliva, G., Vigliotta, G., Cicatelli, A., Guarino, F., Guidi Nissim, W., Labra, M., & Castiglione, S. (2025). Urban phytoremediation: A nature-based solution for environmental reclamation and sustainability. Plants, 14(13), 2057. https://doi.org/10.3390/plants14132057

Diringer, S. E., Feingold, B. J., Ortiz, E. J., Gallis, J. A., Araújo-Flores, J. M., Berky, A., Pan, W. K. Y., & Hsu-Kim, H. (2015). River transport of mercury from artisanal and small-scale gold mining and risks for dietary mercury exposure in Madre de Dios, Peru. Environmental Science: Processes & Impacts, 17(2), 478–487. https://doi.org/10.1039/c4em00567h

Donkor, A. K., Bonzongo, J. C., Nartey, V. K., & Adotey, D. K. (2006). Mercury in different environmental compartments of the Pra River Basin, Ghana. Science of The Total Environment, 368(1), 164–176. https://doi.org/10.1016/j.scitotenv.2005.09.046

Donkor, A. K., Ghoveisi, H., & Bonzongo, J.-C. J. (2024). Use of metallic mercury in artisanal gold mining by amalgamation: A review of temporal and spatial trends and environmental pollution. Minerals, 14(6), 555. https://doi.org/10.3390/min14060555

Dordaa, S. D. D. P., Gordon, C., Nukpezah, D., Anang, A. K., & Kwawu, M. S. A. (2025). Assessing risks of methylmercury contamination in the Ankobra estuary, Western Region, Ghana. International Journal of Environmental Studies, 1–16. https://doi.org/10.1080/00207233.2025.2586283

Dossou Etui, I. M., Stylo, M., Davis, K., Evers, D. C., Slaveykova, V. I., Wood, C., & Burton, M. E. H. (2024). Artisanal and small-scale gold mining and biodiversity: a global literature review. Ecotoxicology, 33(4–5), 484–504. https://doi.org/10.1007/s10646-024-02748-w

Egendorf, S. P., Gailey, A. D., Schachter, A. E., & Mielke, H. W. (2020). Soil toxicants that potentially affect children’s health. Current Problems in Pediatric and Adolescent Health Care, 50(1), 100741. https://doi.org/https://doi.org/10.1016/j.cppeds.2019.100741

Esdaile, L. J., & Chalker, J. M. (2018). The mercury problem in artisanal and small‐Scale gold mining. Chemistry – A European Journal, 24(27), 6905–6916. https://doi.org/10.1002/chem.201704840

Förstner, U. (2004). Sediment dynamics and pollutant mobility in rivers: An interdisciplinary approach. Lakes & Reservoirs: Science, Policy and Management for Sustainable Use, 9(1), 25–40. https://doi.org/10.1111/j.1440-1770.2004.00231.x

Gerson, J. R., Topp, S. N., Vega, C. M., Gardner, J. R., Yang, X., Fernandez, L. E., Bernhardt, E. S., & Pavelsky, T. M. (2020). Artificial lake expansion amplifies mercury pollution from gold mining. Science Advances, 6(48). https://doi.org/10.1126/sciadv.abd4953

Han, D., Cheng, J., Hu, X., Jiang, Z., Mo, L., Xu, H., Ma, Y., Chen, X., & Wang, H. (2017). Spatial distribution, risk assessment and source identification of heavy metals in sediments of the Yangtze River Estuary, China. Marine Pollution Bulletin, 115(1), 141–148. https://doi.org/https://doi.org/10.1016/j.marpolbul.2016.11.062

Karikari, A. Y., Duah, A. A., Akurugu, B. A., & Darko, H. F. (2021). Assessing the impacts of artisanal mining on the quality ofvf South-western Rivers System in Ghana. Environmental Monitoring and Assessment, 193(11). https://doi.org/10.1007/s10661-021-09515-y

Kumar, V., Umesh, M., Shanmugam, M. K., Chakraborty, P., Duhan, L., Gummadi, S. N., Pasrija, R., Jayaraj, I., & Dasarahally Huligowda, L. K. (2023). A retrospection on mercury contamination, bioaccumulation, and toxicity in diverse environments: Current insights and future prospects. Sustainability, 15(18), 13292. https://doi.org/10.3390/su151813292

Lin, Y., Larssen, T., Vogt, R. D., Feng, X., & Zhang, H. (2011). Transport and fate of mercury under different hydrologie regimes in polluted stream in mining area. Journal of Environmental Sciences, 23(5), 757–764. https://doi.org/10.1016/s1001-0742(10)60473-1

Liu, Q., Gao, J., Li, G., Zheng, Y., Li, R., & Yue, T. (2024). Bibliometric analysis on mercury emissions from coal-fired power plants: a systematic review and future prospect. Environmental Science and Pollution Research, 31(13), 19148–19165. https://doi.org/10.1007/s11356-024-32369-z

Ma, M., Du, H., & Wang, D. (2019). Mercury methylation by anaerobic microorganisms: A review. Critical Reviews in Environmental Science and Technology, 49(20), 1893–1936. https://doi.org/10.1080/10643389.2019.1594517

Martinez, G., McCord, S. A., Driscoll, C. T., Todorova, S., Wu, S., Araújo, J. F., Vega, C. M., & Fernandez, L. E. (2018). Mercury contamination in riverine sediments and fish associated with artisanal and small-scale gold mining in Madre de Dios, Peru. International Journal of Environmental Research and Public Health, 15(8), 1584. https://doi.org/10.3390/ijerph15081584

Navarro, A. (2008). Review of characteristics of mercury speciation and mobility from areas of mercury mining in semi-arid environments. Reviews in Environmental Science and Bio/Technology, 7(4), 287–306. https://doi.org/10.1007/s11157-008-9139-6

Outridge, P. M., Mason, R. P., Wang, F., Guerrero, S., & Heimbürger-Boavida, L. E. (2018). Updated global and oceanic mercury budgets for the United Nations Global Mercury Assessment 2018. Environmental Science & Technology. https://doi.org/10.1021/acs.est.8b01246

Pang, Q., Gu, J., Wang, H., & Zhang, Y. (2022). Global health impact of atmospheric mercury emissions from artisanal and small-scale gold mining. IScience, 25(9). https://doi.org/10.1016/j.isci.2022.104881

Przybyla, J., McClure, P. R., Zaccaria, K. J., & Pohl, H. R. (2021). Chemical interactions and mixtures in public health risk assessment: An analysis of ATSDR’s interaction profile database. Regulatory Toxicology and Pharmacology, 125, 104981. https://doi.org/https://doi.org/10.1016/j.yrtph.2021.104981

Regnell, O., & Watras, C. J. (2018). Microbial mercury methylation in aquatic environments: A critical review of published field and laboratory studies. Environmental Science & Technology, 53(1), 4–19. https://doi.org/10.1021/acs.est.8b02709

Rinaldi, M., Wyżga, B., & Surian, N. (2005). Sediment mining in alluvial channels: Physical effects and management perspectives. River Research and Applications, 21(7), 805–828. https://doi.org/10.1002/rra.884

Sall, M. L., Diaw, A. K. D., Gningue-Sall, D., Efremova Aaron, S., & Aaron, J.-J. (2020). Toxic heavy metals: impact on the environment and human health, and treatment with conducting organic polymers, a review. Environmental Science and Pollution Research, 27(24), 29927–29942. https://doi.org/10.1007/s11356-020-09354-3

Selin, H., Keane, S. E., Wang, S., Selin, N. E., Davis, K., & Bally, D. (2018). Linking science and policy to support the implementation of the Minamata Convention on Mercury. Ambio, 47(2), 198–215. https://doi.org/10.1007/s13280-017-1003-x

Spiller, P., van Wijngaarden, E., Adams, H. R., Strain, J. J., McSorley, E. M., Mulhern, M. S., Conway, M. C., Yeates, A. J., Carrington, C., Bolger, P. M., Morgan, K. M., Taylor, C. M., Ralston, N. V. C., Crawford, M. A., Hibbeln, J. R., Brenna, J. T., & Myers, G. J. (2023). Net effects explains the benefits to children from maternal fish consumption despite methylmercury in fish. NeuroToxicology, 99, 195–205. https://doi.org/https://doi.org/10.1016/j.neuro.2023.10.010

Tripathee, L., Guo, J., Kang, S., Paudyal, R., Huang, J., Sharma, C. M., Zhang, Q., Chen, P., Ghimire, P. S., & Sigdel, M. (2019). Spatial and temporal distribution of total mercury in atmospheric wet precipitation at four sites from the Nepal-Himalayas. Science of The Total Environment, 655, 1207–1217. https://doi.org/10.1016/j.scitotenv.2018.11.338

UN Environment Programme. (2019). Global Mercury Assessment 2018. UN Environment Programme Economy Division Chemicals and Health Branch International Environment House. https://wedocs.unep.org/handle/20.500.11822/27579

Verbrugge, B., & Thiers, R. (2016). Artisanal and small-scale mining. In Breaking New Ground (pp. 313–334). Routledge. https://doi.org/10.4324/9781315541501-17

WHO. (2011). Guidelines for drinking-water quality. In WHO Press (Vol. 1, Issue 5, pp. 1–515). WHO Press. https://doi.org/10.1248/jhs1956.35.307

Wu, Y.-S., Osman, A. I., Hosny, M., Elgarahy, A. M., Eltaweil, A. S., Rooney, D. W., Chen, Z., Rahim, N. S., Sekar, M., Gopinath, S. C. B., Mat Rani, N. N. I., Batumalaie, K., & Yap, P.-S. (2024). The toxicity of mercury and its chemical compounds: Molecular mechanisms and environmental and human health implications: A comprehensive review. ACS Omega, 9(5), 5100–5126. https://doi.org/10.1021/acsomega.3c07047

Yan, J., Li, R., Wang, C., Yang, S., Shao, M., Zhang, L., Li, P., & Feng, X. (2025). Transport and transformation of colloidal and particulate mercury in contaminated watershed. Water Research, 278, 123428. https://doi.org/https://doi.org/10.1016/j.watres.2025.123428

Zhang, Y., & Adeloju, S. B. (2008). A novel sequential injection—Cold vapour atomic absorption spectrometric system for rapid and reliable determination of mercury. Talanta, 74(4), 951–957. https://doi.org/https://doi.org/10.1016/j.talanta.2007.07.043

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Published

2026-06-15

How to Cite

Hatika, R. G., Dewata, I., Karno, R., Daruwati, I., & Hidayah, F. (2026). Linking Mercury Contamination to Transport Dynamics in an Indonesian River: A Data-Driven Engineering Framework for ASGM-Impacted Watersheds. Journal of Applied Engineering and Technological Science (JAETS), 7(2), 1423-1437. https://doi.org/10.37385/jaets.v7i2.9121